人物簡介
出生年月：1978年7月
學歷、職稱： 博士，副教授
專業方向：有機化學
教育與研究經歷
1996.9－2000.6 武漢大學化學系本科
2000.9－2005.6 武漢大學化學與分子科學學院碩博連讀
2005.7－ 武漢大學化學與分子科學學院有機化學研究所
研究領域與興趣
目前主要從事過渡金屬催化的有機反應的方法學、機理和動力學等方面的研究。
教育科研
教學情況
承擔動力與機械學院、土木建築工程學院、生命科學學院及印刷包裝工程系等專業物理化學、有機化學課程教學及化學與分子科學學院研究生儀器分析實驗教學。
承擔項目與課題
主持國家自然科學基金兩項：
1.過渡金屬催化有機反應中金屬交換和還原換消除的動力學研究
2.過渡金屬催化的偶聯反應中金屬交換及相關競爭反應的動力學研究
參加國家自然科學基金兩項：
3.自由基聚合物作為高功率電極材料的套用基礎研究
4.兩次金屬交換促進的新型偶聯反應
代表性成果
1.Zhang Heng, Luo Xiancai, Kittiya Wongkhan, Duan Hui, Li Qiang, Zhu Lizheng, Wang Jian, Andrei S. Batsanov, Judith A. K. Howard, Todd B. Marder, Lei Aiwen,Acceleration of Reductive Elimination of [Ar-Pd-Csp3] by a Phosphine/Electron–Deficient Olefin Ligand: A Kinetic Investigation, Chemistry-A European Journal2009, 15, 3823-3829.
2.Jin Liqun, Zhao Yingsheng, Zhu Lizheng, Zhang Heng*, Lei Aiwen*, Highly Selective Palladium-Catalyzed Oxidative Csp2-Csp3 Cross-Coupling of Arylzinc and Alkylindium Reagents through Double Transmetallation, Advanced Synthesis & Catalysis, 2009, 351, 630-634.
3.Liu Jing, Wang Haibo, Zhang Heng, Wu Xiaojun, Zhang Hua, Deng Yi, Yang Zhen, Lei aiwen, Identification of a Highly Efficient Alkylated Pincer Thioimido–Palladium(II) Complex as the Active Catalyst in Negishi Coupling, Chemistry-A European Journal2009, 15, 4437-4445.
4.Yin Weiyan, He Chuan, Chen Mao, Zhang Heng, Lei Aiwen, Nickel-catalyzed oxidative coupling reactions of two different terminal alkynes using O2 as the oxidant at room temperature: facile syntheses of unsymmetric 1,3-diynes, Organic Letter 2009, 11, 709-712.
5.Shi Wei, Luo Yingdong, Luo Xiancai, Chao Lei, Zhang Heng, Wang Jian, Lei Aiwen, Investigation of an Efficient Palladium-Catalyzed C(sp)-C(sp) Cross-Coupling Reaction Using Phosphine-Olefin Ligand: Application and Mechanistic Aspects,J. Am. Chem. Soc. 2008, 130, 14713-14720.
6.Luo Xiancai, Zhang Heng, Duan Hui, Liu Qiang, Zhu Lizheng, Zhang Tony, Lei Aiwen, Superior Effect of a p-Acceptor Ligand (Phosphine-Electron-Deficient Olefin Ligand) in the Negishi Coupling Involving Alkylzinc Reagents,Organic Letter2007, 9, 4571-4574.
7.Zhang Heng, Liu Yuwen, Wang Cunxin, Analysis of the Calibration Constant of a Heat Conduction Calorimeter, Instrumentation Science and Technology, 2006, 34, 379-392.
10.張恆, 汪存信, 介紹一種處理動力學數據的新方法, 大學化學, 2009, 24(6), 65-67.
